Nickel‐Catalyzed Enantioselective Conjunctive Cross‐Coupling of 9‐BBN Borates. Issue 39 (17th August 2017)

• Record Type: Journal Article
• Authors: Chierchia, Matteo; Law, Chunyin; Morken, James P.
• Is Part Of: Angewandte Chemie international edition. Volume 56:Issue 39(2017)
• Page Start: 11870
• Page End: 11874
• Publication Date: 2017-08-17
• Subjects: asymmetric catalysis -- boron -- cross coupling -- nickel; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201706719
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: Catalytic enantioselective conjunctive cross‐coupling between 9‐BBN borate complexes and aryl electrophiles can be accomplished with Ni salts in the presence of a chiral diamine ligand. The reactions furnish chiral 9‐BBN derivatives in an enantioselective fashion and these are converted to chiral alcohols and amines, or engaged in other stereospecific C−C bond forming reactions. Abstract : Conjunctive coupling : Ni‐Catalyzed conjunctive couplings furnish chiral 9‐BBN derivatives in an enantioselective fashion and these are converted to chiral alcohols and amines, or they can be engaged in other stereospecific C−C bond forming reactions.