Interfacial Synthesis of Electrically Conducting Palladium Bis(dithiolene) Complex Nanosheet. Issue 8 (1st July 2015)

• Record Type: Journal Article
• Authors: Pal, Tigmansu; Kambe, Tetsuya; Kusamoto, Tetsuro; Foo, Maw Lin; Matsuoka, Ryota; Sakamoto, Ryota; Nishihara, Hiroshi
• Is Part Of: ChemPlusChem. Volume 80:Issue 8(2015:Aug.)
• Page Start: 1255
• Page End: 1258
• Publication Date: 2015-07-01
• Subjects: electrochemistry -- nanostructures -- thin films -- transition metals -- synthesis design; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/cplu.201500206
• Languages: English
• ISSNs: 2192-6506

Abstract

Abstract: The synthesis of palladium bis(dithiolene) complex nanosheets (PdDt) possessing a kagome‐type lattice structure was performed via interfacial reaction between metal salt in aqueous phase and dithiolato ligand in organic phase. The PdDt nanosheets were characterised by AFM, STM, TEM revealing flat and sheet‐like morphology; IR, UV spectroscopy show the corresponding coordination connectivity between metal and ligand, followed by powder X‐ray diffraction and SAED, which determined nanosheets to be structurally similar to previously reported nickel bis(dithiolene) complex nanosheets NiDt. Abstract : Got it covered! The synthesis of palladium bis(dithiolene) coordination nanosheets (CONASH) has been achieved by both liquid–liquid and gas–liquid interfacial reactions between a metal salt in the aqueous phase and a ligand dissolved in the organic phase (see figure).