Intramolecular Frustrated Lewis Pair with the Smallest Boryl Site: Reversible H2 Addition and Kinetic Analysis1. Issue 6 (17th December 2014)

• Record Type: Journal Article
• Authors: Chernichenko, Konstantin; Kótai, Bianka; Pápai, Imre; Zhivonitko, Vladimir; Nieger, Martin; Leskelä, Markku; Repo, Timo
• Is Part Of: Angewandte Chemie international edition. Volume 54:Issue 6(2015)
• Page Start: 1749
• Page End: 1753
• Publication Date: 2014-12-17
• Subjects: aminoboranes -- density functional calculations -- frustrated Lewis pairs -- kinetics -- thermodynamics; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201410141
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: Ansa ‐aminoborane1 ( ortho ‐TMPC6 H4 BH2 ; TMP=2, 2, 6, 6‐tetramethylpiperid‐1‐yl), a frustrated Lewis pair with the smallest possible Lewis acidic boryl site (BH2 ), is prepared. Although it is present in quenched forms in solution, and BH2 represents an acidic site with reduced hydride affinity, 1 reacts with H2 under mild conditions producing ansa ‐ammonium trihydroborate2 . The thermodynamic and kinetic features as well as the mechanism of this reaction are studied by variable‐temperature NMR spectroscopy, spin‐saturation transfer experiments, and DFT calculations, which provide comprehensive insight into the nature of1 . Abstract : As simple as that : An intramolecular frustrated Lewis pair that consists of a very simple acidic boryl site (BH2 ) and a bulky amino group is found to split dihydrogen in a fast and reversible process. Spin‐saturation transfer NMR techniques were used to measure the reaction rates and to obtain accurate kinetic parameters.