On the Evaluation of the Average Crystalline Size and Surface Area of Platinum Catalyst Nanoparticles. Issue 10 (30th August 2018)

• Record Type: Journal Article
• Authors: Leontyev, Igor N.; Kuriganova, Alexandra B.; Allix, Mathieu; Rakhmatullin, Aydar; Timoshenko, Pavel E.; Maslova, Olga A.; Mikheykin, Alexey S.; Smirnova, Nina V.
• Is Part Of: Physica status solidi. Volume 255:Issue 10(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2018-08-30
• Subjects: average nanoparticle size -- catalysts -- Pt/C -- specific surface area -- X‐ray diffraction; Solid state physics -- Periodicals; Solids -- Periodicals; Atomic structure -- Periodicals; 530.41
• DOI: 10.1002/pssb.201800240
• Languages: English
• ISSNs: 0370-1972

Abstract

Abstract : In the present work, the effect of grain size distribution on the diffraction profile shape is inspected via analysis of the mutual ratio of Lorentz and Gauss components in pseudo‐Voigt function which is used for simulating X‐ray profiles of nanoparticles. As established from the plotted dependences, the error in the average Pt nanoparticles size determination reaches 56% and the discrepancy between calculated Pt nanoparticle surface areas attains 60%. Furthermore, the determination error becomes greater with increasing the Lorentz contribution to pseudo‐Voigt function, or, in fact, with enlarging particle size distribution. The empirically found electrochemical surface area of Pt/C electrocatalyst is compared with that evaluated from XRD data using the Scherrer formula and particle size distribution data analysis. Abstract : In this work, on the basis of analysis of the diffraction profiles of X‐ray diffraction patterns and the particle size distributions, it is shown that the use of only a well‐known Scherrer formula without analyzing the particle size distributions can lead to an error in the average Pt nanoparticles size determination reaching 56%, and the discrepancy between calculated Pt nanoparticle surface areas attains 60%.