Planar Metasurfaces Enable High‐Efficiency Colored Perovskite Solar Cells. Issue 10 (26th August 2018)

• Record Type: Journal Article
• Authors: Liu, Dong; Wang, Lin; Cui, Qingyu; Guo, L. Jay
• Is Part Of: Advanced science. Volume 5:Issue 10(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2018-08-26
• Subjects: metasurfaces -- nanometer thick films -- perovskite solar cells -- simple planar structure; Science -- Periodicals; 505
• DOI: 10.1002/advs.201800836
• Languages: English
• ISSNs: 2198-3844

Abstract

Abstract: The achievement of perfect light absorption in ultrathin semiconductor materials is not only a long‐standing goal, but also a critical challenge for solar energy applications, and thus requires a redesigned strategy. Here, a general strategy is demonstrated both theoretically and experimentally to create a planar metasurface absorber comprising a 1D ultrathin planar semiconductor film (replacing the 2D array of subwavelength elements in classical metasurfaces), a transparent spacer, and a metallic back reflector. Guided by derived formulisms, a new type of macroscopic planar metasurface absorber is experimentally demonstrated with light near‐perfectly and exclusively absorbed by the ultrathin semiconductor film. To demonstrate the power and simplicity of this strategy, a prototype of a planar metasurface solar cell is experimentally demonstrated. Furthermore, the device model predicts that a colored planar metasurface perovskite solar cell can maintain 75% of the efficiency of its black counterpart despite the use of a perovskite film that is one order of magnitude thinner. The displayed cell colors have high purities comparable to those of state‐of‐the‐art color filters, and are insensitive to viewing angles up to 60°. The general theoretical framework in conjunction with experimental demonstrations lays the foundation for designing miniaturized, planar, and multifunctional solar cells and optoelectronic devices. Abstract : A type of macroscopic planar metasurface absorber with light near‐perfectly and exclusively absorbed by the ultrathin semiconductor film is theoretically and experimentally demonstrated via a general strategy. Guided by this strategy, colored perovskite solar cells are further designed to meet all the desired characteristics including high power conversion efficiency, high‐purity, tunability, and angle‐insensitive colors.