Self-assembly of a Si-based cage by the formation of 24 equivalent covalent bonds. Issue 84 (4th October 2018)
- Record Type:
- Journal Article
- Title:
- Self-assembly of a Si-based cage by the formation of 24 equivalent covalent bonds. Issue 84 (4th October 2018)
- Main Title:
- Self-assembly of a Si-based cage by the formation of 24 equivalent covalent bonds
- Authors:
- Holmes, Jessica L.
Abrahams, Brendan F.
Ahveninen, Anna
Boughton, Berin A.
Hudson, Timothy A.
Robson, Richard
Thinagaran, Dinaiz - Abstract:
- Abstract : A covalent, robust, nano-sized tetrahedral cage containing six silicon centres has been synthesised and structurally characterised. Abstract : A robust, nano-sized covalent cage, of composition, [(PhSi)6 (ctc)4 ] 6− (H6 ctc = cyclotricatechylene) has been prepared in a simple reaction in good yield. The tetrahedral anionic cage is stable in both the solid and solution state and exhibits an affinity for Cs + ions which bind to the internal surface of the cage.
- Is Part Of:
- Chemical communications. Volume 54:Issue 84(2018)
- Journal:
- Chemical communications
- Issue:
- Volume 54:Issue 84(2018)
- Issue Display:
- Volume 54, Issue 84 (2018)
- Year:
- 2018
- Volume:
- 54
- Issue:
- 84
- Issue Sort Value:
- 2018-0054-0084-0000
- Page Start:
- 11877
- Page End:
- 11880
- Publication Date:
- 2018-10-04
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c8cc06405a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 8020.xml