Recent advances in the Pd(II)-catalyzed asymmetric addition of arylboronic acids to electron-deficient olefins. Issue 46 (14th November 2018)

• Record Type: Journal Article
• Authors: Wu, Liang; Shen, Jiefeng; Yang, Guoqiang; Zhang, Wanbin
• Is Part Of: Tetrahedron letters. Volume 59:Issue 46(2018)
• Page Start: 4055
• Page End: 4062
• Publication Date: 2018-11-14
• Subjects: Palladium -- Arylboronic acids -- Electron-deficient olefins -- Asymmetric catalysis -- Benzylic chiral centers; Chemistry, Organic -- Periodicals; 547.005
• DOI: 10.1016/j.tetlet.2018.10.013
• Languages: English
• ISSNs: 0040-4039

Abstract

Graphical abstract: Highlights: Summary of Pd(II)-catalyzed asymmetric arylation of electron-deficient olefins. Catalytic behaviours of different catalytic systems have been discussed. Future challenges in this field have been discussed. Abstract: Palladium is a relatively inexpensive transition metal when compared with rhodium, and is thus more attractive for industrial applications. However, the development of Pd(II) catalyst systems for the asymmetric addition of arylboronic acids to electron-deficient olefins was not as widely developed as Rh(I) catalytic systems until recent years. Several new and efficient Pd(II) catalyst systems have been developed in this decade, enabling the asymmetric additions of arylboronic acids to different types of substrates. This brief review summarizes and discusses recent works related to the Pd(II)-catalyzed asymmetric addition of arylboronic acids to electron-deficient olefins.