Palladium-catalyzed addition reaction of thioesters to norbornenes. Issue 37 (16th September 2015)
- Record Type:
- Journal Article
- Title:
- Palladium-catalyzed addition reaction of thioesters to norbornenes. Issue 37 (16th September 2015)
- Main Title:
- Palladium-catalyzed addition reaction of thioesters to norbornenes
- Authors:
- Arisawa, Mieko
Tanii, Saori
Yamada, Tomoki
Yamaguchi, Masahiko - Abstract:
- Abstract: A palladium complex derived from Pd2 (dba)3 and tris(2, 4, 6-trimethoxyphenyl)phosphine catalyzes the addition reaction of thioesters to norbornenes, giving trans -2-acyl -3-organothionorbornanes. The trans -adducts are predominantly obtained with the acyl group at the endo -position and the organothio group at the exo- position. Aroyl and heteroaroyl thioesters as well as alkanoyl thioesters were reacted, including S -(4-tolyl) phenylthioglyoxylate and methyl 2-(4-tolylthio)-2-oxo-acetate. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 71:Issue 37(2015)
- Journal:
- Tetrahedron
- Issue:
- Volume 71:Issue 37(2015)
- Issue Display:
- Volume 71, Issue 37 (2015)
- Year:
- 2015
- Volume:
- 71
- Issue:
- 37
- Issue Sort Value:
- 2015-0071-0037-0000
- Page Start:
- 6449
- Page End:
- 6458
- Publication Date:
- 2015-09-16
- Subjects:
- Addition reaction -- Thioesters -- Norbornenes -- Palladium
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2015.05.042 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 7975.xml