Branched/linear selectivity in palladium-catalyzed allyl-allyl cross-couplings: the role of ligands. Issue 37 (16th September 2015)
- Record Type:
- Journal Article
- Title:
- Branched/linear selectivity in palladium-catalyzed allyl-allyl cross-couplings: the role of ligands. Issue 37 (16th September 2015)
- Main Title:
- Branched/linear selectivity in palladium-catalyzed allyl-allyl cross-couplings: the role of ligands
- Authors:
- Ardolino, Michael J.
Morken, James P. - Abstract:
- Abstract: While Pd-catalyzed allyl-allyl cross-couplings in the presence of small-bite-angle bidentate ligands reliably furnish the branched regioisomer with high levels of selectivity, cross-couplings in the presence of large-bite-angle bidentate ligands give varying, often unpredictable, levels of selectivity. In a combined computational and experimental study, we probe the underlying features that govern the regioselectivity in these metal-catalyzed cross-couplings. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 71:Issue 37(2015)
- Journal:
- Tetrahedron
- Issue:
- Volume 71:Issue 37(2015)
- Issue Display:
- Volume 71, Issue 37 (2015)
- Year:
- 2015
- Volume:
- 71
- Issue:
- 37
- Issue Sort Value:
- 2015-0071-0037-0000
- Page Start:
- 6409
- Page End:
- 6413
- Publication Date:
- 2015-09-16
- Subjects:
- Bite angle -- Cross-coupling -- Allylation -- Pd catalysis
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2015.05.015 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 7975.xml