Bifunctional CoNi/CoFe2O4 /Ni foam electrodes for efficient overall water splitting at a high current density. Issue 39 (1st October 2018)

• Record Type: Journal Article
• Authors: Li, Shasha; Sirisomboonchai, Suchada; Yoshida, Akihiro; An, Xiaowei; Hao, Xiaogang; Abudula, Abuliti; Guan, Guoqing
• Is Part Of: Journal of materials chemistry. Volume 6:Issue 39(2018)
• Page Start: 19221
• Page End: 19230
• Publication Date: 2018-10-01
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c8ta08223e
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : An electrocatalyst composed of CoNi(hydroxide) nanosheets and flower-like CoFe2 O4 particles with multiple porous structure is successfully deposited on nickel foam and applied for overall water splitting. Abstract : It is always a challenge to develop a kind of low-cost electrode with high activity and superior durability for both the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in the electrolysis of water at a high current density. In this study, a novel electrocatalyst composed of earth abundant metals of Ni, Fe, and Co with a three-dimensional (3D) nanostructure and high activity was successfully fabricated on a Ni foam (NF) substrate through a facile hydrothermal synthesis method followed by electrodeposition. The electrode had three levels of porous structures, including the bottom supermacroporous NF substrate, flower-like CoFe2 O4 with a macroporous structure, and the topmost mesoporous nanosheets of CoNi(oxy)hydroxide. Since this hierarchical architecture of CoNi/CoFe2 O4 /NF was binder-free, more catalytic active sites could be exposed, leading to enhanced electron transport and providing open-channels for the effective release of gas. As a result, CoNi/CoFe2 O4 /NF showed highly efficient electrocatalytic activity toward OER with an overpotential of 360 (±5) mV to achieve a current density as high as 1000 mA cm −2 in an alkaline medium. Meanwhile, as a cathode catalyst, it also exhibited excellent performance toward HER with overpotentials as low as 82 (±3) and 189 (±3) mV to deliver current densities of 10 and 100 mA cm −2, respectively. Furthermore, when it was applied as a bifunctional catalyst for overall water splitting, current densities of 10 mA cm −2 and 100 mA cm −2 were obtained at applied potentials of 1.57 and 1.75 V, respectively, together with excellent durability.