Computational modelling of void growth in Phenolic Molding Compounds filled PolyPropylene from optical measurements. (October 2018)

• Record Type: Journal Article
• Authors: Caro, A.S.; Bernardeau, F.; Perrin, D.; Leger, R.; Benezet, J.C.; Ienny, P.
• Is Part Of: Polymer testing. Volume 71(2018)
• Page Start: 209
• Page End: 216
• Publication Date: 2018-10
• Subjects: Phenolic molding compounds -- Damage -- Volume change -- Finite element; Polymers -- Testing -- Periodicals; Polymères -- Tests -- Périodiques; 620.1920287
• DOI: 10.1016/j.polymertesting.2018.09.008
• Languages: English
• ISSNs: 0142-9418

Abstract

Abstract: Phenolic molding compounds (PMC), also known as Bakelite™, are the first synthetic plastics ever produced. They are still in use today in electrical, household and automotive applications. However, one major drawback of PMC is their lack of recycling option. Indeed, landfilling is still the main route of disposal, which constitutes a serious environmental burden. A new alternative recycling method is the use of comminuted PMC as filler in a thermoplastic matrix, in order to improve its mechanical and thermal properties. Several key parameters of the manufactured composite structure are the fillers size distributions, their loading percentage, and the adhesion at the filler/matrix interface. These parameters are related to mechanical properties of the composites, such as tensile strength. In this work, a polypropylene matrix is filled with 20% by weight of comminuted PMC (d50 = 24 μm) functionalized with 3% by weight of PP-g-MA to improve matrix/fillers compatibility. A FE model was developed from the mechanical behavior of each component. PP matrix and PMC fillers are individually characterized from tensile tests instrumented with photomechanics for the matrix characterization and their behaviors were modelled through a set of numerical parameters (elasto-visco-plasticity with a Gurson criterion behavior for the matrix and damage elasticity for the fillers). Numerical simulations at several strain rates were conducted on representative volume element with various microstructures. Comparison between the determinist model results and the experimental data (strength, volumetric variation) shows that this type of modelling could be a predictive tool in order to design particulate composites with optimized mechanical properties. Hence, it is an adequate way to understand micromechanisms of deformation (damage, cavitation). Highlights: Phenolic molding compounds, non-recyclable, are friendly fillers for PP polymer as they improve mechanical and thermal properties. The main breakage mechanism is matrix cavitation inside and around the fillers. As compatibilizer is added, the fillers concentrate matrix damage thus limiting its cavitation and the premature rupture of the composite.