RGO/KMn8O16 composite as supercapacitor electrode with high specific capacitance. Issue 4 (March 2016)

• Record Type: Journal Article
• Authors: Guan, Hongtao; Dang, Wenhui; Chen, Gang; Dong, Chengjun; Wang, Yude
• Is Part Of: Ceramics international. Volume 42:Issue 4(2016)
• Page Start: 5195
• Page End: 5202
• Publication Date: 2016-03
• Subjects: A: Powders: chemical preparation -- B: Nanostructures -- C: Electrochemical properties -- D: Transitional metal oxides; Ceramics -- Periodicals; Céramique industrielle -- Périodiques; Ceramics; Periodicals; Electronic journals; 666
• DOI: 10.1016/j.ceramint.2015.12.043
• Languages: English
• ISSNs: 0272-8842

Abstract

Abstract: Reduced graphene oxide/cryptomelane (RGO/KMn8 O16 ) composites are successfully synthesized from α-MnO2 nanorods and GO using a water-bathing precipitation method. The unique structure of KMn8 O16 nanorods, with a length of 2–4 μm, dispersed on the surface of RGO leads to a much enhanced electrical conductivity and ionic transport, finally achieving composites with an improved electrochemical performance. Electrochemical measurement results show a specific capacitance of 222.3 F/g at a current density of 0.2 A/g, much higher than that of the original α-MnO2 . After 500 cycles at 2.0 A/g, the RGO/KMn8 O16 composite electrode still retains 92.6% of its initial specific capacitance. The excellent electrochemical performance and durability observed for this composite electrode suggest its potential application for electrochemical capacitors.