Dating the Martian meteorite Zagami by the 87Rb‐87Sr isochron method with a prototype in situ resonance ionization mass spectrometer. (14th December 2014)

• Record Type: Journal Article
• Authors: Scott Anderson, F.; Levine, Jonathan; Whitaker, Tom J.
• Is Part Of: Rapid communications in mass spectrometry. Volume 29:Number 2(2015)
• Page Start: 191
• Page End: 204
• Publication Date: 2014-12-14
• Subjects: Mass spectrometry -- Periodicals; 543.65
• DOI: 10.1002/rcm.7095
• Languages: English
• ISSNs: 0951-4198

Abstract

Abstract : RATIONALE: The geologic history of the Solar System builds on an extensive record of impact flux models, crater counts, and ~270 kg of lunar samples analyzed in terrestrial laboratories. However, estimates of impactor flux may be biased by the fact that most of the dated Apollo samples were only tenuously connected to an assumed geologic context. Moreover, uncertainties in the modeled cratering rates are significant enough to lead to estimated errors for dates on Mars and the Moon of ~1 Ga. Given the great cost of sample return missions, combined with the need to sample multiple terrains on multiple planets, we have developed a prototype instrument that can be used for in situ dating to better constrain the age of planetary samples. METHODS: We demonstrate the first use of laser ablation resonance ionization mass spectrometry for 87 Rb‐ 87 Sr isochron dating of geological specimens. The demands of accuracy and precision have required us to meet challenges including regulation of the ambient temperature, measurement of appropriate backgrounds, sufficient ablation laser intensity, avoidance of the defocusing effect of the plasma created by ablation pulses, and shielding of our detector from atoms and ions of other elements. RESULTS: To test whether we could meaningfully date planetary materials, we have analyzed a piece of the Martian meteorite Zagami. In each of four separate measurements we obtained 87 Rb‐ 87 Sr isochron ages for Zagami consistent with its published age, and, in both of two measurements that reached completion, we obtained better than 200 Ma precision. Combining all our data into a single isochron with 581 spot analyses gives an 87 Rb‐ 87 Sr age for this specimen of 360 ±90 Ma. CONCLUSIONS: Our analyses of the Zagami meteorite represent the first successful application of resonance ionization mass spectrometry to isochron geochronology. Furthermore, the technique is miniaturizable for spaceflight and in situ dating on other planetary bodies. © 2014 The Authors. Rapid Communications in Mass Spectrometry published by John Wiley & Sons, Ltd.