Continuous flow adsorption of methylene blue by cellulose nanocrystal-alginate hydrogel beads in fixed bed columns. (20th January 2016)

• Record Type: Journal Article
• Authors: Mohammed, Nishil; Grishkewich, Nathan; Waeijen, Herman Ambrose; Berry, Richard M.; Tam, Kam Chiu
• Is Part Of: Carbohydrate polymers. Volume 136(2016)
• Page Start: 1194
• Page End: 1202
• Publication Date: 2016-01-20
• Subjects: Adsorption -- Fixed bed column -- Cellulose nanocrystals -- Alginate -- Hydrogel beads; Polysaccharides -- Periodicals; Polysaccharides -- Periodicals; Polysaccharides -- Périodiques; Electronic journals; 547.78
• DOI: 10.1016/j.carbpol.2015.09.099
• Languages: English
• ISSNs: 0144-8617

Abstract

Graphical abstract: Highlights: An unusual fixed bed column breakthrough profile was observed. Anomalous bed expansion and shrinkage was elucidated. Hydrogel beads Qm was found to be 255.5 mg/g. Abstract: The adsorption behavior of methylene blue by cellulose nanocrystal-alginate (CNC-ALG) hydrogel beads in a fixed bed column was studied by varying the initial dye concentrations, bed depths and flow rates. An unusual phenomenon was observed in the early phase of the adsorption, and the phenomenon was elucidated by varying other critical design parameters, such as the flow direction, diameter of column and composition of adsorbent. The swelling and shrinkage of hydrogel beads during the adsorption was responsible for the anomalous concentration versus time profile of the adsorption process. The maximum adsorption capacity of the column was 255.5 mg/g, which is in agreement with the batch study determined from the Langmuir adsorption isotherm. A comprehensive understanding on the adsorption mechanism of CNC-ALG hydrogel beads during the early stages of adsorption was derived from this study.