Mechanical properties of natural rubber nanocomposites reinforced with high aspect ratio cellulose nanocrystals isolated from soy hulls. (20th November 2016)

• Record Type: Journal Article
• Authors: Flauzino Neto, Wilson Pires; Mariano, Marcos; da Silva, Ingrid Souza Vieira; Silvério, Hudson Alves; Putaux, Jean-Luc; Otaguro, Harumi; Pasquini, Daniel; Dufresne, Alain
• Is Part Of: Carbohydrate polymers. Volume 153(2016)
• Page Start: 143
• Page End: 152
• Publication Date: 2016-11-20
• Subjects: Cellulose nanocrystals -- Soy hulls -- Agro-industrial residue -- Natural rubber -- Aspect ratio -- Nanocomposites; Polysaccharides -- Periodicals; Polysaccharides -- Periodicals; Polysaccharides -- Périodiques; Electronic journals; 547.78
• DOI: 10.1016/j.carbpol.2016.07.073
• Languages: English
• ISSNs: 0144-8617

Abstract

Highlights: High aspect ratio CNC was extracted from soy hulls. Mild acid hydrolysis conditions are preferable to improve yield and preserve crystallinity. CNC reinforced NR nanocomposites were prepared. High mechanical performance nanocomposites were obtained. Sedimentation of CNC plays a major role in the mechanical properties. Abstract: Cellulose nanocrystals (CNCs) were isolated from soy hulls by acid sulfuric hydrolysis. The resulting CNCs were characterized using TEM, AFM, WAXS, elemental analysis and TGA. The CNCs have a high crystallinity, specific surface area and aspect ratio. The aspect ratio (around 100) is the largest ever reported in the literature for a plant cellulose source. These CNCs were used as a reinforcing phase to prepare nanocomposite films by casting/evaporation using natural rubber as matrix. The mechanical properties were studied in both the linear and non-linear ranges. The reinforcing effect was higher than the one observed for CNCs extracted from other sources. It may be assigned not only to the high aspect ratio of these CNCs but also to the stiffness of the percolating nanoparticle network formed within the polymer matrix. Moreover, the sedimentation of CNCs during the evaporation step was found to play a crucial role on the mechanical properties.