A Ferrocenyl Amino Substituted Stannylene as an Intramolecular Fe→Sn Lewis Adduct. Issue 17 (30th August 2018)
- Record Type:
- Journal Article
- Title:
- A Ferrocenyl Amino Substituted Stannylene as an Intramolecular Fe→Sn Lewis Adduct. Issue 17 (30th August 2018)
- Main Title:
- A Ferrocenyl Amino Substituted Stannylene as an Intramolecular Fe→Sn Lewis Adduct
- Authors:
- Förster, Christoph
Becker, Patrick M.
Heinze, Katja - Abstract:
- Abstract : The acyclic ferrocenyl amino substituted stannylene Sn[N(Fc)SiMe3 ]2 1 was synthesized from tin(II) chloride and in situ formed LiN(Fc)(SiMe3 ). The molecular structure of1 in the solid state shows two short intramolecular Fe··· Sn contacts suggesting electron donation of the iron(II) atoms to the tin(II) atom as double intramolecular metal‐only Lewis base/Lewis acid adduct. Density functional theory (DFT) calculations support this Fe→Sn stabilizing effect. Abstract :
- Is Part Of:
- Zeitschrift für anorganische und allgemeine Chemie. Volume 644:Issue 17(2018)
- Journal:
- Zeitschrift für anorganische und allgemeine Chemie
- Issue:
- Volume 644:Issue 17(2018)
- Issue Display:
- Volume 644, Issue 17 (2018)
- Year:
- 2018
- Volume:
- 644
- Issue:
- 17
- Issue Sort Value:
- 2018-0644-0017-0000
- Page Start:
- 1057
- Page End:
- 1063
- Publication Date:
- 2018-08-30
- Subjects:
- Stannylene -- Ferrocene -- Metal‐only Lewis base -- Lewis acids -- Tin -- Iron
Chemistry, Inorganic -- Periodicals
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3749 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/zaac.201800269 ↗
- Languages:
- English
- ISSNs:
- 0044-2313
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 9452.000000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 7741.xml