Parametric Optimization of Experimental Conditions for Dye-Sensitized Solar Cells based on Far-red Sensitive Squaraine Dye. (April 2016)

• Record Type: Journal Article
• Authors: Morimoto, Takuya; Fujikawa, Naotaka; Ogomi, Yuhei; Pandey, Shyam S.; Hayase, Shuzi
• Is Part Of: Journal of physics. Volume 704(2016)
• Publication Date: 2016-04
• Subjects: Physics -- Congresses; 530.5
• DOI: 10.1088/1742-6596/704/1/012002
• Languages: English
• ISSNs: 1742-6588

Abstract

Abstract: A far-red sensitive unsymmetrical squaraine dye SQ-41 has been synthesized and subjected to the fabrication of dye-sensitized solar cells by varying the various parameters in order attain optimum photoconversion efficiency (η). It has been demonstrated that an optimum ratio of dye to coadsorber, thickness of mesoporous TiO2 layer, redox electrolyte and surface treatment are necessary to enhance overall external η. In the case of surface treatment, it has been shown to exhibit pronounced device performance when both of the FTO as well mesoporous TiO2 surfaces were treated with aqueous TiCl4 . In spite of very high molar extinction coefficient of dye SQ-41, 10-12 µm thickness of mesoporous TiO2 was found to be necessary to attain the maximum η.