Au70S20(PPh3)12: an intermediate sized metalloid gold cluster stabilized by the Au4S4 ring motif and Au-PPh3 groups12. Issue 3 (8th December 2017)
- Record Type:
- Journal Article
- Title:
- Au70S20(PPh3)12: an intermediate sized metalloid gold cluster stabilized by the Au4S4 ring motif and Au-PPh3 groups12. Issue 3 (8th December 2017)
- Main Title:
- Au70S20(PPh3)12: an intermediate sized metalloid gold cluster stabilized by the Au4S4 ring motif and Au-PPh3 groups12
- Authors:
- Kenzler, Sebastian
Schrenk, Claudio
Frojd, Andrew R.
Häkkinen, Hannu
Clayborne, Andre Z.
Schnepf, Andreas - Abstract:
- Abstract : Reducing (Ph3 P)AuSC(SiMe3 )3 withl -Selectride® gives the medium-sized metalloid gold cluster Au70 S20 (PPh3 )12 . Abstract : Reducing (Ph3 P)AuSC(SiMe3 )3 withl -Selectride® gives the medium-sized metalloid gold cluster Au70 S20 (PPh3 )12 . Computational studies show that the phosphine bound Au-atoms not only stabilize the electronic structure of Au70 S20 (PPh3 )12, but also behave as electron acceptors leading to auride-like gold atoms on the exterior.
- Is Part Of:
- Chemical communications. Volume 54:Issue 3(2018)
- Journal:
- Chemical communications
- Issue:
- Volume 54:Issue 3(2018)
- Issue Display:
- Volume 54, Issue 3 (2018)
- Year:
- 2018
- Volume:
- 54
- Issue:
- 3
- Issue Sort Value:
- 2018-0054-0003-0000
- Page Start:
- 248
- Page End:
- 251
- Publication Date:
- 2017-12-08
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc08014j ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 7757.xml