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A new and facile approach to 1, 2-dihydroisoquinolin-3(4H)-imines by the Cu(i)-catalyzed reaction of 2-ethynylbenzyl methanesulfonates, sulfonyl azides and amines. Issue 1 (19th December 2017)
Record Type:
Journal Article
Title:
A new and facile approach to 1, 2-dihydroisoquinolin-3(4H)-imines by the Cu(i)-catalyzed reaction of 2-ethynylbenzyl methanesulfonates, sulfonyl azides and amines. Issue 1 (19th December 2017)
Main Title:
A new and facile approach to 1, 2-dihydroisoquinolin-3(4H)-imines by the Cu(i)-catalyzed reaction of 2-ethynylbenzyl methanesulfonates, sulfonyl azides and amines
Abstract : A new, step-economical and operationally simple access to unsubstituted 1, 2-dihydroisoquinolin-3(4 H )-imines by Cu-catalyzed MCRs under mild conditions is described. Abstract : A new, step-economical and operationally simple access to unsubstituted 1, 2-dihydroisoquinolin-3(4 H )-imines by Cu-catalyzed MCRs under mild conditions is described. In addition, selective hydrolysis of imines to the corresponding 1, 2-dihydroisoquinolin-3(4 H )-ones under refluxed conc. HCl has also been investigated.