Three dimensionally-ordered 2D MoS2 vertical layers integrated on flexible substrates with stretch-tunable functionality and improved sensing capability. Issue 37 (13th September 2018)

• Record Type: Journal Article
• Authors: Islam, Md Ashraful; Kim, Jung Han; Ko, Tae-Jun; Noh, Chanwoo; Nehate, Shraddha; Kaium, Md Golam; Ko, Minjee; Fox, David; Zhai, Lei; Cho, Chang-Hee; Sundaram, Kalpathy B.; Bae, Tae-Sung; Jung, YounJoon; Chung, Hee-Suk; Jung, Yeonwoong
• Is Part Of: Nanoscale. Volume 10:Issue 37(2018)
• Page Start: 17525
• Page End: 17533
• Publication Date: 2018-09-13
• Subjects: Nanoscience -- Periodicals; Nanotechnology -- Periodicals; 620.505
• DOI: 10.1039/c8nr05362f
• Languages: English
• ISSNs: 2040-3364

Abstract

Abstract : Three-dimensionally flexible vertical 2D MoS2 layers are reported. Abstract : The intrinsically anisotropic crystallinity of two-dimensional (2D) transition metal dichalcogenide (2D TMD) layers enables a variety of intriguing material properties which strongly depend on the physical orientation of constituent 2D layers. For instance, 2D TMDs with vertically-aligned layers exhibit numerous dangling bonds on their 2D layer edge sites predominantly exposed on the surface, projecting significantly improved physical and/or chemical adsorption capability compared to their horizontally-oriented 2D layer counterparts. Such property advantages can be further promoted as far as the material can be integrated onto unconventional substrates of tailored geometry/functionality, offering vast opportunities for a wide range of applications which demand enhanced surface area/reactivity and mechanical flexibility. Herein, we report a new form of 2D TMDs, i.e., three-dimensionally ordered 2D molybdenum disulfide (2D MoS2 ) with vertically-aligned layers integrated on elastomeric substrates and explore their tunable multi-functionalities and technological promise. We grew large-scale (>2 cm 2 ) vertically-aligned 2D MoS2 layers using a three-dimensionally patterned silicon dioxide (SiO2 ) template and directly transferred/integrated them onto flexible polydimethylsiloxane (PDMS) substrates by taking advantage of the distinguishable water-wettability of 2D MoS2 vs . SiO2 . The excellent structural integrity of the integrated vertical 2D MoS2 layers was confirmed by extensive spectroscopy/microscopy characterization. In addition, the stretch-driven unique tunability of their optical and surface properties was also examined. Moreover, we applied this material for flexible humidity sensing and identified significantly improved (>10 times) sensitivity over conventionally-designed horizontal 2D MoS2 layers, further confirming their high potential for unconventional flexible technologies.