A water-stable homochiral luminescent MOF constructed from an achiral acylamide-containing dicarboxylate ligand for enantioselective sensing of penicillamine. Issue 77 (12th September 2018)

• Record Type: Journal Article
• Authors: Zhang, Qingfu; Lei, Mingyuan; Kong, Fang; Yang, Yan
• Is Part Of: Chemical communications. Volume 54:Issue 77(2018)
• Page Start: 10901
• Page End: 10904
• Publication Date: 2018-09-12
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c8cc06274a
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A water-stable homochiral luminescent MOF was obtained by spontaneous symmetry-breaking crystallization from achiral precursors; it exhibits enantioselective sensing ofd /l -Pen. Abstract : A water-stable homochiral luminescent metal–organic framework (HLMOF), {[Cd(l )(4, 4′-bipy)]·DMA·5H2 O} n (1 ), was obtained by a spontaneous symmetry-breaking crystallization from achiral precursors without any enantiopure auxiliary. The homochirality of1 was confirmed by single-crystal X-ray diffraction and CD spectroscopy. Complex1 exhibits an interesting enantioselective sensing ofd /l -penicillamine in water.