Diffusion of lithium ions and diffusion-induced stresses in a phase separating electrode under galvanostatic and potentiostatic operations: Phase field simulations. (December 2015) - Song, Y.C.
Highlights: Discuss the phase separation of Li-rich and Li-poor phases in lithium ion batteries. Study the mechanism of phase separation, e.g. impacts of different energies. Li-ion diffusion and stress in single phase electrode is sensitive to charge operation. Phase separating electrode is not so sensitive to charge operation. Phase separation is suggested to be avoided according to diffusion and stress. Abstract: Phase separation in an electrode of a lithium ion battery, which is a phenomenon where an active electrode material is separated into Li-rich and Li-poor phases, exists widely in many active materials and has significant impacts on the diffusion of lithium ions and diffusion-induced stresses. A phase field model is developed to study the phase separation. Firstly, the influences of various energies, such as the free energy of uniform Li-ion concentration, gradient energy and elastic energy, on phase separation are discussed. Secondly, the impacts of charge operation, e.g. galvanostatic and potentiostatic, on Li-ion diffusion and diffusion-induced stresses in a planar phase separating electrode are investigated. Calculations are also made for single phase electrodes based on Fick's law for comparison. The obtained simulation results show that the Li-ion diffusion in a phase separating electrode depends significantly on the phase separating profile and movement of phase boundary, but it is not sensitive to charge operation. The diffusion-induced stresses also separate into high and low stress regions. Finally, based on the diffusion process and diffusion-induced stress, it is suggested that phase separation should be avoided for the sake of fast charging and mechanical reliability.