Growth, structural, optical, thermal and mechanical properties of cytosinium hydrogen selenite: A novel nonlinear optical single crystal. (June 2016)

• Record Type: Journal Article
• Authors: Jaikumar, P.; Sathiskumar, S.; Balakrishnan, T.; Ramamurthi, K.
• Is Part Of: Materials research bulletin. Volume 78(2016)
• Page Start: 96
• Page End: 102
• Publication Date: 2016-06
• Subjects: A. Optical materials -- B. Crystal growth -- C. Thermogravimetric analysis (TGA) -- C. Infrared spectroscopy -- D. Dielectric properties; Materials -- Periodicals; Crystal growth -- Periodicals; Matériaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Crystal growth; Materials; Periodicals; 620.11
• DOI: 10.1016/j.materresbull.2016.02.019
• Languages: English
• ISSNs: 0025-5408

Abstract

Graphical abstract: Highlights: Growth of bulk single crystals of cytosinium hydrogen selenite (CHS) is reported. Dielectric constant of CHS is measured as a function of Frequency and temperature. Lower cut off value of UV–vis-NIR spectrum of CHS crystal is observed at 210 nm. Meyer's index value of CHS crystal calculated identifies it as a soft material. Powder SHG efficiency of CHS is about 1.5 times that of KDP crystal. Abstract: A novel nonlinear optical single crystal of cytosinium hydrogen selenite was grown from aqueous solution of cytosinium hydrogen selenite by slow solvent evaporation method at room temperature. The structural properties of grown crystal have been studied by single crystal and powder X-ray diffraction analysis. Presence of various functional groups was identified from Fourier transform infrared spectroscopy. The optical transmittance and absorbance spectra were recorded by UV–vis-NIR spectrometer and the grown crystal possesses good transparency in the entire visible region. The dielectric constant and dielectric loss of the crystal were calculated as a function of frequency at different temperatures. The mechanical strength of the cytosinium hydrogen selenite crystal was estimated using Vicker's microhardness tester. Etch patterns of the cytosinium hydrogen selenite crystal were obtained using distilled water as etchant for different etching time. Second harmonic generation efficiency tested using Nd:YAG laser is about 1.5 times that of KDP.