Photochemical and electrochemical hydrogen evolution reactivity of lanthanide-functionalized polyoxotungstates. Issue 74 (30th August 2018)

• Record Type: Journal Article
• Authors: Arab Fashapoyeh, Marzieh; Mirzaei, Masoud; Eshtiagh-Hosseini, Hossein; Rajagopal, Ashwene; Lechner, Manuel; Liu, Rongji; Streb, Carsten
• Is Part Of: Chemical communications. Volume 54:Issue 74(2018)
• Page Start: 10427
• Page End: 10430
• Publication Date: 2018-08-30
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c8cc06334f
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : The first example of molecular lanthanide tungstate clusters for photochemical and electrochemical hydrogen evolution catalysis is reported. Abstract : The first example of hydrogen evolution reactivity (HER) of lanthanide-functionalized Keggin-based polyoxotungstates under photochemical and electrochemical conditions is reported. The HER activity under homogeneous, visible light-driven conditions and under heterogeneous, electrochemical conditions depends on the type of lanthanide functionalization, so that a new class of model HER catalysts for systematic reactivity studies is now accessible.