Towards the use of experimental electron densities to estimate reliable lattice energies. Issue 36 (17th August 2018)

• Record Type: Journal Article
• Authors: Spackman, Mark A.
• Is Part Of: CrystEngComm. Volume 20:Issue 36(2018)
• Page Start: 5340
• Page End: 5347
• Publication Date: 2018-08-17
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c8ce01108g
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : Lattice energies derived from experimental charge densities are critically assessed, with a view to encouraging further research of this nature. Abstract : We examine the reliability of lattice energies (and by inference, intermolecular interaction energies) estimated from experimental electron densities. Based on the modest number of results published to date, lattice energies obtained in this fashion typically overestimate more reliable values, sometimes by hundreds of kJ mol −1 . The causes of this behaviour are explored in detail, and include a misunderstanding of the contribution of the polarization energy, the failure to recognise the important link to a sublimation process, and the use of inappropriate atom–atom potentials to estimate dispersion and exchange-repulsion energies. It is hoped that this contribution will encourage further research of this nature, and a more critical evaluation of energies derived from high-quality diffraction experiments on molecular crystals.