Investigation into the lignin decomposition mechanism by analysis of the pyrolysis product of Pinus radiata. (November 2016)

• Record Type: Journal Article
• Authors: Kim, Young-Min; Jae, Jungho; Myung, Soyoung; Sung, Bong Hyun; Dong, Jong-In; Park, Young-Kwon
• Is Part Of: Bioresource technology. Volume 219(2016)
• Page Start: 371
• Page End: 377
• Publication Date: 2016-11
• Subjects: Lignin -- Pyrolysis mechanism -- GPC -- NMR; Biomass -- Periodicals; Biomass energy -- Periodicals; Bioremediation -- Periodicals; Agricultural wastes -- Periodicals; Factory and trade waste -- Periodicals; Organic wastes -- Periodicals; Bioénergie -- Périodiques; Déchets agricoles -- Périodiques; Déchets industriels -- Périodiques; Déchets organiques -- Périodiques; Déchets (Combustible) -- Périodiques; 662.88
• DOI: 10.1016/j.biortech.2016.08.001
• Languages: English
• ISSNs: 0960-8524

Abstract

Highlights: Lignin pyrolysis mechanism was studied by the product analysis of Pinus radiata. Methoxy phenols and pyrolytic lignin were main primary pyrolyzates. Dealkoxylated phenols were increased by enhanced demethoxylation of alkoxyphenols. Aromatics were produced by dehydroxylation and condensation reaction at 575 °C. Abstract: Lignin pyrolysis chemistry was investigated via the analysis of the products obtained from the fast pyrolysis of a pine wood at different temperatures. Methoxy phenols, such as guaiacols and eugenols, were produced mainly at 375 and 475 °C, while non-methoxy phenols, such as alkyl phenols and pyrocatechols were dominant at 525 and 575 °C. At 575 °C, aromatic hydrocarbons were formed together with larger amounts of light hydrocarbon gases. When the temperature was increased from 375 and 475 °C, the yield of pyrolytic lignin was increased, whereas its average molecular weight was decreased. At 525 °C, smaller molecular pyrolytic lignin with a maximum concentration of phenolic hydroxyl groups was produced due to the increased secondary cracking of the reaction intermediates. On the other hand, at 575 °C, larger molecular pyrolytic lignin with smaller amounts of phenolic hydroxyl groups was produced due to the increased condensation activity of the pyrolysis reaction intermediates.