Microwave curing of alkali-activated binder using hwangtoh without calcination. (15th November 2015)

• Record Type: Journal Article
• Authors: Kim, Baek-Joong; Yi, Chongku; Kang, Kyung-In
• Is Part Of: Construction & building materials. Volume 98(2015)
• Page Start: 465
• Page End: 475
• Publication Date: 2015-11-15
• Subjects: Hwangtoh -- Alkali activation -- Microwave curing -- Physical properties -- XRD -- 29Si solid-state NMR; Building materials -- Periodicals; 624.18
• DOI: 10.1016/j.conbuildmat.2015.08.119
• Languages: English
• ISSNs: 0950-0618

Abstract

Highlights: Microwave dramatically shortened curing period of AAHP compared to the conventional heat. Microwave promoted formation of more stable product than the conventional heat. Temperature profile inside the microwave cured specimen was opposite to that under the conventional heat. XRD analysis indicated kaolinite and halloysite in microwave-cured AAHP transformed to hydroxysodalite. 29 Si NMR also indicated that the prominent Q 4 Si phase in microwave-cured AAHP is hydroxysodalite. Abstract: Microwaves were used to accelerate the curing of alkali activated hwangtoh paste (AAHP); the resulting compressive strength, porosity and composition were then compared against conventional heat-cured specimens. This found that a compressive strength of ∼20 MPa can be developed within 4 h, versus 72 h with conventional heat. While the 29 Si NMR analysis showed the similar trends in the chemical shift with the curing time, the MIP results showed that the microwave-cured AAHP contained a greater cumulative pore volume and mean pore size than the conventional thermal-cured AAHP of the equal strength. The compressive strength of microwave-cued AAHP was attributed to the formation of a well-crystallized hydroxysodalite phase and an internal temperature gradient generated during curing.