A quadrafunctional electrocatalyst of nickel/nickel oxide embedded N-graphene for oxygen reduction, oxygen evolution, hydrogen evolution and hydrogen peroxide oxidation reactions. Issue 9 (18th July 2018)

• Record Type: Journal Article
• Authors: Faisal, Shaikh Nayeem; Haque, Enamul; Noorbehesht, Nikan; Liu, Hongwei; Islam, Md. Monirul; Shabnam, Luba; Roy, Anup Kumar; Pourazadi, Ehsan; Islam, Mohammod S.; Harris, Andrew T.; Minett, Andrew I.
• Is Part Of: Sustainable energy & fuels. Volume 2:Issue 9(2018)
• Page Start: 2081
• Page End: 2089
• Publication Date: 2018-07-18
• Subjects: Renewable energy sources -- Periodicals; Fuel cells -- Periodicals; Electric batteries -- Periodicals; Electrochemistry -- Periodicals; 660.297
• DOI: 10.1039/c8se00068a
• Languages: English
• ISSNs: 2398-4902

Abstract

Abstract : A multifunctional nano-heterostructured electrocatalyst of transition metal/metal oxide (nickel/nickel oxide) embedded on nitrogen-doped graphene is reported. Abstract : A multifunctional nano-heterostructured electrocatalyst of transition metal/metal oxide (nickel/nickel oxide) embedded on nitrogen-doped graphene is reported. The hybrid composite of N-doped graphene nanosheets with a high atomic percentage of nitrogen (8.2 at%) and embedded with highly distributed nickel/nickel oxide nanoparticles inside the graphene layers is synthesized by a one pot thermal annealing process. The resultant composite demonstrates excellent electrocatalytic activity utilizing the superior electrocatalytic properties of nickel/nickel oxide nanoparticles supported on nitrogen-doped graphene. The hybrid exhibits efficient oxygen reduction reaction (ORR) properties comparable with state-of-the-art electrode Pt/C with a four-electron transfer pathway and superior oxygen evolution reaction (OER) compared to the state-of-the-art electrode for the OER, Ru/C. Alternatively, this composite acts as an excellent electrode material for the hydrogen evolution reaction (HER) both in acidic and alkaline media. Nevertheless, this composite facilitates the hydrogen peroxide oxidation reaction (HPOR) in the presence of hydrogen peroxide, which is crucial for developing reversible fuel cells and fuel cells with liquid oxidant.