On the dynamics of transition metal migration and its impact on the performance of layered oxides for sodium-ion batteries: NaFeO2 as a case study. Issue 31 (19th July 2018)

• Record Type: Journal Article
• Authors: Silván, Begoña; Gonzalo, Elena; Djuandhi, Lisa; Sharma, Neeraj; Fauth, François; Saurel, Damien
• Is Part Of: Journal of materials chemistry. Volume 6:Issue 31(2018)
• Page Start: 15132
• Page End: 15146
• Publication Date: 2018-07-19
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c8ta02473a
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : Reversibility of transition metal migration in layered oxides as cathodes for sodium ion batteries at the expense of polarization increase. Abstract : Transition metal (TM) layered oxides constitute one of the most promising families of compounds for the cathode of Na-ion batteries. However, their structural stability at the charged state is a critical performance limiting factor, which is believed to be closely related to irreversible TM migration into the Na layers. Nevertheless, experimental evidence of this TM migration and its influence on the electrochemical performance is still scarce, while the understanding of such a phenomenon constitutes a key step for developing better performing TM layered oxides. Here NaFeO2 has been studied as a model system, since it is expected to produce one of the most pronounced TM migrations and provide possibly one of the highest theoretical energy densities of TM layered oxides. By combining the Potential Intermittent Titration Technique (PITT), Electrochemical Impedance Spectroscopy (EIS) and operando X-ray diffraction, it has been possible to analyze the structural evolution of Na x FeO2, track the iron migration and observe its influence on the insertion capacity and Na diffusivity.