Preparation of hyperbranched polymer via single electron transfer living radical polymerization. Issue 1 (June 2015)

• Record Type: Journal Article
• Authors: Zhang, X; Chen, X H; Li, J; Cao, X X; Cheng, C J
• Is Part Of: IOP conference series. Volume 87:Issue 1(2015)
• Publication Date: 2015-06
• Subjects: Materials science -- Periodicals; 620.1105
• DOI: 10.1088/1757-899X/87/1/012091
• Languages: English
• ISSNs: 1757-8981

Abstract

Abstract: α-Trichloromethyl benzyl alcohol is converted to α-trichloromethyl benzyl methacrylate in 62% yield under esterification conditions. The ester proves to be a good inimer to prepare hyperbranched polymer by utilizing SET-LRP approach. The monomer conversion is about 72% at 60°C for 6 h.