Cu(I)/Ag(I)-mediated decarboxylative trifluoromethylation of arylpropiolic acids with Me3SiCF3 at room temperature. Issue 27 (7th July 2016)
- Record Type:
- Journal Article
- Title:
- Cu(I)/Ag(I)-mediated decarboxylative trifluoromethylation of arylpropiolic acids with Me3SiCF3 at room temperature. Issue 27 (7th July 2016)
- Main Title:
- Cu(I)/Ag(I)-mediated decarboxylative trifluoromethylation of arylpropiolic acids with Me3SiCF3 at room temperature
- Authors:
- Yang, Lingling
Jiang, Linlin
Li, Yaming
Fu, Xinmei
Zhang, Rong
Jin, Kun
Duan, Chunying - Abstract:
- Abstract: A novel Cu(I)/Ag(I)-mediated decarboxylative trifluoromethylation of arylpropiolic acids with Me3 SiCF3 has been developed for the construction of Csp-CF3 bond under mild conditions. This method proceeds smoothly at room temperature and shows a widely functional compatibility, providing a series of corresponding trifluoromethylated acetylenyl-containing aromatics in good yields. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 72:Issue 27/28(2016)
- Journal:
- Tetrahedron
- Issue:
- Volume 72:Issue 27/28(2016)
- Issue Display:
- Volume 72, Issue 27/28 (2016)
- Year:
- 2016
- Volume:
- 72
- Issue:
- 27/28
- Issue Sort Value:
- 2016-0072-NaN-0000
- Page Start:
- 3858
- Page End:
- 3862
- Publication Date:
- 2016-07-07
- Subjects:
- Trifluoromethylation -- Decarboxylative coupling reaction -- Arylpropiolic acids -- Trifluoromethylated acetylenes -- Cu(I)/Ag(I)-mediated
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2016.05.012 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 7515.xml