An effective surface modification of carbon fiber for improving the interfacial adhesion of polypropylene composites. (25th December 2015)

• Record Type: Journal Article
• Authors: Liu, Yuan; Zhang, Xue; Song, Chenchen; Zhang, Yuanyuan; Fang, Yichao; Yang, Bin; Wang, Xinling
• Is Part Of: Materials & design. Volume 88(2015:Dec.)
• Page Start: 810
• Page End: 819
• Publication Date: 2015-12-25
• Subjects: Surface treatment -- Carbon fiber -- Maleic anhydride grafted PP -- Thermoplastic composite; Materials -- Periodicals; Engineering design -- Periodicals; Matériaux -- Périodiques; Conception technique -- Périodiques; Electronic journals; 620.11
• DOI: 10.1016/j.matdes.2015.09.100
• Languages: English
• ISSNs: 0264-1275

Abstract

Abstract: A simple and effective modification for carbon fiber (CF) was presented in our work. CF was coated with ethylene–methyl acrylate–glycidyl methacrylate (E–MA–GMA) terpolymer through solution dipping. A uniform layer of 2.0 wt.% E–MA–GMA was confirmed on CF by IR, TGA and SEM. XPS showed that surface oxygen-containing functional groups were obviously increased after modification, which were advantageous to promote the reactivity of CFs. The treatment turned out to be helpful in enhancing the interfacial adhesion by micro-droplet experiment and the interfacial shear strength was 157% higher. The physical properties of PP/mCF composites were improved by static and dynamic mechanical analysis and the improvement was more noteworthy when maleic anhydride grafted PP (MAPP) was added to the matrix, which was consistent with the fracture morphology. The ultimate flexural strength, impact energy and tensile strength were increased by 139.3%, 233.9% and 126.1%. Besides, the mechanical performance of PP composites with 0–30 wt.% CFs were all significantly enhanced by CF surface treatment in combination with MAPP modification. We believed that the excellent performance was not caused by fiber length or crystallinity, it was mainly due to the superior interfacial interaction by intermolecular chain entanglement, as well as chemical reaction between E–MA–GMA and MAPP. Graphical abstract: Highlights: CFs were modified by solution dipping method using E–MA–GMA. CF surface treatment and MAPP addition notably increased the interfacial interaction. The improved interfacial adhesion led to superior mechanical performance. The interfacial enhancement mechanism was discussed.