Competition between oxidation and anti-oxidation to guarantee visible light activity for a TiO2–x photocatalyst from the dissolution of Ti0. (10th August 2015)

• Record Type: Journal Article
• Authors: Jiang, Jinghui; Zhou, Han; Ding, Jian; Zhang, Fan; Fan, Tongxiang; Zhang, Di
• Is Part Of: International journal of hydrogen energy. Volume 40:Number 30(2015)
• Page Start: 9155
• Page End: 9164
• Publication Date: 2015-08-10
• Subjects: Dissolution degree -- Oxidation and anti-oxidation -- Visible light activity -- Water splitting; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2015.05.115
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: In this study, we investigated the critical factor for promoting visible light photocatalytic hydrogen evolution using a TiO2 photocatalyst, which limits the amount of Ti 3+ coexisting with the catalyst. Our goal was to establish a simple and cost effective oxidation and anti-oxidation competitive strategy to synthesize a TiO2-x photocatalyst containing Ti 0, Ti 2+, Ti 3+, and Ti 4+ and an appropriate concentration of Ti 3+ from the oxidation of titanium metal. Finally, the band gap and charge recombination of the final products were successfully optimized by the cooperation of all of the components to achieve efficient visible light photocatalytic hydrogen evolution without the addition of any exogenous dopants, and an ideal quantum yield of approximately 4.28% was achieved at a wavelength of 480 nm. Although various methods have been attempted to preserve Ti 3+, our strategy for preserving Ti 3+ from the initial preparation to the final products represents a new approach to alter the activity of TiO2 . Highlights: Optimal Ti 3+ concentration leads to the best visible light activity. Oxidation and anti-oxidation competitive strategy was explored to preserve Ti 3+ . H2 SO4 and EG results in the optimal oxidation and anti-oxidation system.