An experimental and computational study on isomerically pure, soluble azaphthalocyanines and their complexes and boron azasubphthalocyanines of a varying number of aza units. Issue 35 (31st August 2018)

• Record Type: Journal Article
• Authors: Liebold, Martin; Sharikow, Eugen; Seikel, Elisabeth; Trombach, Lukas; Harms, Klaus; Zimcik, Petr; Novakova, Veronika; Tonner, Ralf; Sundermeyer, Jörg
• Is Part Of: Organic & biomolecular chemistry. Volume 16:Issue 35(2018)
• Page Start: 6586
• Page End: 6599
• Publication Date: 2018-08-31
• Subjects: Chemistry, Organic -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1039/c8ob01705k
• Languages: English
• ISSNs: 1477-0520

Abstract

Abstract : Step by step insertion of aza units into non-aggregating isomerically pure azasubphthalocyanines N x -[Spc*BCl] and azaphthalocyanines N x -[Pc*M]: a systematic experimental and computational study on HOMO and LUMO energies. Abstract : Herein, we present a series of isomerically pure, peripherally alkyl substituted, soluble and low aggregating azaphthalocyanines as well as their new, smaller hybrid homologues, azasubphthalocyanines. The focus lies on the effect of the systematically increasing number of aza building blocks [–N] replacing the non-peripheral [–CH] units and their influence on the physical and photophysical properties of these chromophores. The absolute and relative HOMO–LUMO energies of azaphthalocyanines were analyzed using UV-Vis and CV and compared to the density functional theory calculations (B3LYP, TD-DFT). The lowering of the HOMO level is revealed as the determining factor for the trend in the adsorption energies by electronic structure analysis. Crystals of substituted subphthalocyanines, N2 -Pc*H2 and N4 -[Pc*Zn·H2 O], were obtained out of DCM. For the synthesis of the valuable tetramethyltetralin phthalocyanine building block a new highly efficient synthesis involving a nearly quantitative Co II catalyzed aerobic autoxidation step is introduced replacing inefficient KMnO4 /pyridine as the oxidant.