A facile route to magnetic mesoporous core–shell structured silicas containing covalently bound cyclodextrins for the removal of the antibiotic doxycycline from water. Issue 55 (5th September 2018) - Zhang, Ying
Abstract : The controllable synthesis of a core–shell structured mesoporous organic–inorganic hybrid nanocomposite, Fe3 O4 @SiO2 @mSiO2 -CD, which demonstrates good adsorption of doxycycline. Abstract : The excessive use of antibiotics has led to various environmental problems; the control and separation of these antibiotics are important in environmental science. Herein, a novel mesoporous nanocomposite, Fe3 O4 @SiO2 @mSiO2 -CD, has been synthesized for the removal of antibiotic compounds from aqueous media. The well-designed nanocomposite is composed of β-cyclodextrin functionalized surfaces, ordered mesoporous silica shells with large radially oriented mesopores, and nonporous silica-coated magnetic cores (Fe3 O4 ). The synergistic action of both the mesoporous structure and the accessible cavity of β-cyclodextrin ensures the good adsorption of doxycycline. Furthermore, the Fe3 O4 @SiO2 @mSiO2 -CD nanocomposite can be collected, separated and easily recycled from aqueous solution using an external magnet.