Advanced binder-free electrodes based on CoMn2O4@Co3O4 core/shell nanostructures for high-performance supercapacitors. Issue 55 (10th September 2018)

• Record Type: Journal Article
• Authors: Chen, Xiaobo; Liu, Xiao; Liu, Yongxu; Zhu, Yameng; Zhuang, Guoce; Zheng, Wei; Cai, Zhenyu; Yang, Peizhi
• Is Part Of: RSC advances. Volume 8:Issue 55(2018)
• Page Start: 31594
• Page End: 31602
• Publication Date: 2018-09-10
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c8ra06289g
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : CoMn2 O4 @Co3 O4 core/shell arrays on Ni foam exhibit outstanding electrochemical performance for asymmetric supercapacitors with respect to high specific capacitance and high cycling stability. Abstract : Three-dimensional (3D) hierarchical CoMn2 O4 @Co3 O4 core/shell nanoneedle/nanosheet arrays for high-performance supercapacitors were designed and synthesized on Ni foam by a two-step hydrothermal route. The hybrid nanostructure exhibits much more excellent capacitive behavior compared with either the pristine CoMn2 O4 nanoneedle arrays alone or Co3 O4 nanosheets alone. The formation of an interconnected pore hybrid system is quite beneficial for the facile electrolyte penetration and fast electron transport. The CoMn2 O4 @Co3 O4 electrode can achieve a high specific capacitance of 1627 F g −1 at 1 A g −1 and 1376 F g −1 at 10 A g −1 . In addition, an asymmetric supercapacitor (ASC) was assembled by using the CoMn2 O4 @Co3 O4 core/shell hybrid nanostructure arrays on Ni foam as a positive electrode and activated carbon as a negative electrode in an aqueous 3 M KOH electrolyte. A specific capacitance of 125.8 F g −1 at 1 A g −1 (89.2% retention after 5000 charge/discharge cycles at a current density of 2 A g −1 ) and a high energy density of 44.8 W h kg −1 was obtained. The results indicate that the obtained unique integrated CoMn2 O4 @Co3 O4 nanoarchitecture may show great promise as ASC electrodes for potential applications in energy storage.