Azabora[5]helicene Charge‐Transfer Dyes Show Efficient and Spectrally Variable Circularly Polarized Luminescence. Issue 48 (23rd July 2018)

• Record Type: Journal Article
• Authors: Domínguez, Zoe; López‐Rodríguez, Rocío; Álvarez, Eleuterio; Abbate, Sergio; Longhi, Giovanna; Pischel, Uwe; Ros, Abel
• Is Part Of: Chemistry. Volume 24:Issue 48(2018)
• Page Start: 12660
• Page End: 12668
• Publication Date: 2018-07-23
• Subjects: boron -- circular dichroism -- circularly polarized luminescence -- helicene -- push-pull chromophores; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201801908
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract: Three helicenes based on a borylated arylisoquinoline skeleton have been prepared in their enantiopure forms and characterized with respect to their photophysical properties, including the use of chiroptical spectroscopies. The dyes show varying charge‐transfer characteristics and efficient emission (quantum yields between 0.13 and 0.30, in toluene), which is governed by the electron‐donor substitution ( p ‐MeO‐phenyl, p ‐Me2 N‐phenyl) at the helicene. Marked differences in the emission wavelength and Stokes shift are observed, with the dimethylamino‐substituted derivative emitting most red‐shifted (maximum at ca. 590 nm) and displaying the highest Stokes shift (ca. 6000 cm −1 ) in toluene. The helicenes show electronic circular dichroism (ECD) and significant circularly polarized luminescence (CPL) with dissymmetry factors of up to 3.5×10 −3 . The sign of the ECD band corresponding to the first transition and of the CPL spectrum depend sensibly on the electron‐donor substitution. Abstract : A new twist ! The dye family of borylated arylisoquinolines (BAI dyes) has new members. Enantiopure azabora[5]helicenes with varying charge‐transfer character were prepared and their photophysical properties were determined. Spectrally variable and intense circularly polarized luminescence with high dissymmetry factors was observed. Further, the charge‐transfer character of the dye determines the sign pattern of the chiroptical spectra.