Regenerated cellulose membrane as bio-template for in-situ growth of visible-light driven C-modified mesoporous titania. (1st August 2016)

• Record Type: Journal Article
• Authors: Mohamed, Mohamad Azuwa; W. Salleh, W.N.; Jaafar, Juhana; Mohd Hir, Zul Adlan; Rosmi, Mohamad Saufi; Abd. Mutalib, Muhazri; Ismail, Ahmad Fauzi; Tanemura, Masaki
• Is Part Of: Carbohydrate polymers. Volume 146(2016)
• Page Start: 166
• Page End: 173
• Publication Date: 2016-08-01
• Subjects: Regenerated cellulose membrane -- Bio-template -- Nanoreactor -- In-situ growth -- C-doped mesoporous TiO2 -- Photocatalyst; Polysaccharides -- Periodicals; Polysaccharides -- Periodicals; Polysaccharides -- Périodiques; Electronic journals; 547.78
• DOI: 10.1016/j.carbpol.2016.03.050
• Languages: English
• ISSNs: 0144-8617

Abstract

Graphical abstract: Highlights: C-doped mesoporous TiO2 nanorods synthesized by sol-gel bio-templating method. Regenerated cellulose membrane as nanoreactor and in-situ carbon provider. Environmental friendly, low in cost, and has facile approach. Carbon from RCM was responsible for band-gap narrowing in TiO2 nanorod. Abstract: Visible light driven C-doped mesoporous TiO2 (C-MTiO2 ) nanorods have been successfully synthesized through green, low cost, and facile approach by sol-gel bio-templating method using regenerated cellulose membrane (RCM) as nanoreactor. In this study, RCM was also responsible to provide in-situ carbon sources for resultant C-MTiO2 nanorods in acidified sol at low temperatures. The composition, crystallinity, surface area, morphological structure, and optical properties of C-MTiO2 nanorods, respectively, had been characterized using FTIR, XRD, N2 adsorption/desorption, TEM, UV–vis-NIR, and XPS spectroscopy. The results suggested that the growth of C-MTiO2 nanorods was promoted by the strong interaction between the hydroxyl groups of RCMs and titanium ion. Optical and XPS analysis confirmed that carbon presence in TiO2 nanorods were responsible for band-gap narrowing, which improved the visible light absorption capability. Photocatalytic activity measurements exhibited the capability of C-MTiO2 nanorods in degradation of methyl orange in aqueous solution, with 96.6% degradation percentage under visible light irradiation.