Fabrication and upconversion emission processes in nanoluminophores NaYF4: Er, Yb and NaYF4: Tm, Yb. (9th March 2015)

• Record Type: Journal Article
• Authors: Giang, Lam Thi Kieu; Anh, Tran Kim; Binh, Nguyen Thanh; Minh, Le Quoc; Marciniak, Lukasz; Łojkowski, Witold
• Is Part Of: International journal of nanotechnology. Volume 12:Number 5/6/7(2015)
• Page Start: 538
• Page End: 547
• Publication Date: 2015-03-09
• Subjects: nanoparticles -- NaYF4 -- ytterbium -- erbium -- thulium -- sodium yttrium fluoride -- Er3&#43 -- -- Yb3&#43 -- -- Tm3&#43 -- -- multiphoton upconversion -- soft template -- upconversion luminescence -- UCL nanomaterials -- rare earth elements -- nanotechnology -- morphology -- structure -- emission properties; 620.505
• Languages: English
• ISSNs: 1475-7435

Abstract

In this paper we present the new results of fabrication, characterisation and upconversion emission process of NaYF4 nanoparticles doped with Er 3+ or Tm 3+ and Yb 3+ as sensitiser. In order to fabricate α–, β–NaYF4 :2%Er 3+, 19%Yb 3+ and α–, β–NaYF4 :2%Tm 3+, 19%Yb 3+ nanoparticles the soft template method in isopropylamine at 140C and diethylene glycol (DEG) at 180C has been used. The morphology, structures and emission properties were studied by X–ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and luminescence spectroscopy. The upconversion luminescence (UCL) spectra of α and β crystalline forms of NaYF4 :2%Er 3+, 19%Yb 3+ and NaYF4 :2%Tm 3+, 19%Yb 3+ nanoparticles were investigated upon diode laser excitation at 976 nm. The strong emissions in the green and red spectral regions were observed upon this excitation. The spectral lines of the UCL could be assigned to the upconversion radiative transitions of the Er 3+ or Tm 3+ ions with Yb 3+ sensitiser. The upconversion emission spectra dependent on laser excitation powers have been investigated in order to elucidate the upconversion emission paths which could take place. We found the significant influence of the type of nanocrystalline structure on the upconverting radiative transition mechanisms in NaYF4 :2%Er 3+, 19%Yb 3+ and NaYF4 :2%Tm 3+, 19%Yb 3+ nanoparticles.