Zinc complexes bearing tridentate O, N, O-type half-Salen ligands for ring-opening polymerization of lactide. (5th August 2015)

• Record Type: Journal Article
• Authors: Duan, Ranlong; Gao, Bo; Li, Xiang; Pang, Xuan; Wang, Xianhong; Shao, Huili; Chen, Xuesi
• Is Part Of: Polymer. Volume 71(2015)
• Page Start: 1
• Page End: 7
• Publication Date: 2015-08-05
• Subjects: Zinc -- Half-Salen -- Ring-opening polymerization -- Lactide; Polymers -- Periodicals; Polymerization -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; 547.7
• DOI: 10.1016/j.polymer.2015.06.044
• Languages: English
• ISSNs: 0032-3861

Abstract

Abstract: A number of unreported zinc complexes based on tridentate O, N, O-type half-Salen ligands were prepared. All the complexes were characterized by 1 H, 13 C NMR and elemental analysis. These complexes were used as catalysts with 2-propanol for the ring-opening polymerization ofl -lactide and rac -lactide. They were effective in lactide polymerization with good conversions. And polymerizations were living with the narrow molar mass distributions. The bulky substituents with relatively larger steric hindrance of the ligands coordinated to the central metal centers had relatively low polymerizing activity. Graphical abstract: Highlights: A number of half-Salen zinc Schiff-base complexes were synthesized. These complexes were active in lactide polymerization. The activity of these complexes was closely related to their structures.