Selective vapor‐phase oxidation of o‐xylene to phthalic anhydride over Co‐Mn/H3PW12O40@TiO2 using molecular oxygen as a green oxidant. (20th June 2018)

• Record Type: Journal Article
• Authors: Masoomi, Kianoosh; Ghiaci, Mehran; Botelho do Rego, A.M.
• Is Part Of: Applied organometallic chemistry. Volume 32:Number 9(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2018-06-20
• Subjects: o‐Xylene -- phosphotungstic acid -- phthalic anhydride -- TiO2 -- vapor‐phase oxidation; Organometallic chemistry -- Periodicals; Organometallic compounds -- Periodicals; 547.05
• DOI: 10.1002/aoc.4461
• Languages: English
• ISSNs: 0268-2605

Abstract

Abstract : The oxidation of o ‐xylene to phthalic anhydride over Co‐Mn/H3 PW12 O40 @TiO2 was investigated. The experimental results demonstrated that the prepared catalyst effectively catalyzed the oxidation of o ‐xylene to phthalic anhydride. Also, the synergistic effect between three metals plays vital roles in this reaction. From a green chemistry point of view, this method is environmentally friendly due to carrying out the oxidation in a fixed‐bed reactor under solvent‐free condition and using molecular oxygen as a green and cheap oxidizing agent. The resulting solid catalysts were characterized by FT‐IR, XRD, XPS, ICP‐OES, FESEM, TEM, EDX, DR‐UV spectroscopy, BET and thermogravimetric analysis. The oxidation of o ‐xylene yields four products: o ‐tolualdehyde, phthaldialdehyde, phthalide and finally phthalic anhydride as the main product. The reaction conditions for oxidation of o ‐xylene were optimized by varying the temperature, weight hourly space velocity and oxygen flow rate (contact time). The optimum weight percentage of phosphotungstic acid (HPW) and Co/Mn for phthalic anhydride production were 15 wt % and 2 wt%, respectively. The best Co/Mn ratio was found to be 10/1. Oxygen flow rate was very important on the phthalic anhydride formation. The optimum conditions for oxidation of o ‐xylene were T = 370 °C, WHSV = 0.5 h −1 and oxygen flow rate = 10 mL min −1 . Under optimized conditions, a maximum of 88.2% conversion and 75.5% selectivity to phthalic anhydride was achieved with the fresh catalyst. Moreover, reusability of the catalyst was studied and catalytic activity remained unchanged after at least five cycles. Abstract : The vapor‐phase oxidation of o ‐xylene to phthalic anhydride over Co‐Mn/H3 PW12 O40 @TiO2 under solvent‐free condition and using molecular oxygen as a green oxidizing agent was investigated. The resulting solid catalysts were characterized by several techniques. Also, the reaction conditions for oxidation of o ‐xylene were optimized by varying the temperature, weight hourly space velocity and oxygen flow rate, and under optimized conditions, a maximum of 88.2% conversion and 75.5% selectivity to phthalic anhydride was achieved with the fresh catalyst.