Co-gasification of biosolids with biomass: Thermogravimetric analysis and pilot scale study in a bubbling fluidized bed reactor. (January 2015)

• Record Type: Journal Article
• Authors: Yu, Ming Ming; Masnadi, Mohammad S.; Grace, John R.; Bi, Xiaotao T.; Lim, C. Jim; Li, Yonghua
• Is Part Of: Bioresource technology. Volume 175(2015)
• Page Start: 51
• Page End: 58
• Publication Date: 2015-01
• Subjects: Biosolids -- Biomass -- Co-gasification -- Thermogravimetric analysis -- Bubbling fluidized bed; Biomass -- Periodicals; Biomass energy -- Periodicals; Bioremediation -- Periodicals; Agricultural wastes -- Periodicals; Factory and trade waste -- Periodicals; Organic wastes -- Periodicals; Bioénergie -- Périodiques; Déchets agricoles -- Périodiques; Déchets industriels -- Périodiques; Déchets organiques -- Périodiques; Déchets (Combustible) -- Périodiques; 662.88
• DOI: 10.1016/j.biortech.2014.10.045
• Languages: English
• ISSNs: 0960-8524

Abstract

Highlights: Switchgrass ash rich in potassium catalyzed and enhanced co-gasification reactions. Biosolids minerals interacted with biomass minerals and inhibited gasification. Increasing the feedstocks biosolids proportion adversely affected gasification. No more than 25 wt% biosolids in the fuel feed is recommended. Abstract: This work studied the feasibility of co-gasification of biosolids with biomass as a means of disposal with energy recovery. The kinetics study at 800 °C showed that biomass, such as switchgrass, could catalyze the reactions because switchgrass ash contained a high proportion of potassium, an excellent catalyst for gasification. However, biosolids could also inhibit gasification due to interaction between biomass alkali/alkaline earth metals and biosolids clay minerals. In the pilot scale experiments, increasing the proportion of biosolids in the feedstock affected gasification performance negatively. Syngas yield and char conversion decreased from 1.38 to 0.47 m 3 /kg and 82–36% respectively as the biosolids proportion in the fuel increased from 0% to 100%. Over the same range, the tar content increased from 10.3 to 200 g/m 3, while the ammonia concentration increased from 1660 to 19, 200 ppmv. No more than 25% biosolids in the fuel feed is recommended to maintain a reasonable gasification.