In situ silica–EPDM nanocomposites obtained via reactive processing. (August 2015)

• Record Type: Journal Article
• Authors: Miloskovska, Elena; Hristova-Bogaerds, Denka; van Duin, Martin; de With, Gijsbertus
• Is Part Of: European polymer journal. Volume 69(2015:Aug.)
• Page Start: 260
• Page End: 272
• Publication Date: 2015-08
• Subjects: Rubber–silica composites -- In situ sol–gel reaction -- Silica -- Rubber -- Reactive extrusion; Polymers -- Periodicals; Polymerization -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; Polymerization; Polymers; Periodicals; Electronic journals; 547.705
• DOI: 10.1016/j.eurpolymj.2015.06.010
• Languages: English
• ISSNs: 0014-3057

Abstract

Graphical abstract: Highlights: In situ rubber–silica nanocomposites realized via reactive extrusion. Rubber nanocomposites with uniform dispersion of silica particles. For 3.2% silica composite, modulus ∼120 kPa, similar to conventional nanocomposites, 10% silica. Abstract: In situ rubber nanocomposites prepared via reactive batch mixing and via reactive extrusion were studied. Materials produced via reactive batch mixing showed a significantly higher silica content for a similar reaction time as compared to previously prepared in situ nanocomposites using a diffusion process under static conditions, but an approximately 10% lower modulus over the strain range investigated (0.5–1000%). While the microstructure of the nanocomposites using static conditions was homogeneous with monosized silica particles, the structure of the composites obtained via reactive batch mixing was significantly different, consisting not only of single silica particles but also of aggregates and densely packed silica regions. The nanocomposites obtained via reactive extrusion had a maximum loading of 3.2 wt% silica, possessed a uniform dispersion of silica particles and a similar modulus (≈120 kPa) as conventional nanocomposites, prepared by mixing silica and rubber, containing 10 wt% silica and a coupling agent.