A simple function for the solubility of water in dense-phase carbon dioxide. (January 2015)

• Record Type: Journal Article
• Authors: Aavatsmark, Ivar; Kaufmann, Roland
• Is Part Of: International journal of greenhouse gas control. Volume 32(2015:Jan.)
• Page Start: 47
• Page End: 55
• Publication Date: 2015-01
• Subjects: Carbon dioxide -- Phase behavior -- Solubility -- Thermodynamics; Greenhouse gases -- Environmental aspects -- Periodicals; Air -- Purification -- Technological innovations -- Periodicals; Gaz à effet de serre -- Périodiques; Gaz à effet de serre -- Réduction -- Périodiques; Air -- Purification -- Technological innovations; Greenhouse gases -- Environmental aspects; Periodicals; 363.73874605
• DOI: 10.1016/j.ijggc.2014.11.001
• Languages: English
• ISSNs: 1750-5836

Abstract

Abstract : Highlights: Explicit function for solubility of water in dense-phase carbon dioxide. Approximate temperature range 230–500 K. Approximate pressure range 1–100 MPa. Based on measurements with large uncertainty. Few measurement points for high pressures combined with low temperatures. Abstract: Knowledge of water solubility in dense-phase carbon dioxide is important in CCS projects. An explicit function for the solubility is determined as a function of temperature and pressure. The determination of the function is not based on thermodynamic model assumptions. Only mathematical properties of the measurement data are used in the preparation of the solubility function. The uncertainty in the measurement data has been estimated to 20–30%. The mean deviation of the found function from the measurement data in appropriate subdomains is bounded by 13%. To avoid large deflections in subdomains where measurements are missing, the function has been determined from a system of equations with low condition number.