Production of bio-based 2, 5-furan dicarboxylate polyesters: Recent progress and critical aspects in their synthesis and thermal properties. (October 2016)

• Record Type: Journal Article
• Authors: Papageorgiou, George Z.; Papageorgiou, Dimitrios G.; Terzopoulou, Zoi; Bikiaris, Dimitrios N.
• Is Part Of: European polymer journal. Volume 83(2016:Oct.)
• Page Start: 202
• Page End: 229
• Publication Date: 2016-10
• Subjects: 2, 5-Furan dicarboxylate polyesters -- Synthesis -- Catalysts -- Molecular weights -- Thermal properties -- Crystallization -- Melting -- Thermal stability; AA adipic acid -- ABA 4-acetoxybenzoic acid -- BG 1, 4 butanediol -- BHEFDC bis(hydroxyethyl)-2, 5-furandicarboxylate -- BHFD bis-hydroxy-alkylene furan dicarboxylate -- c(BF)n cyclic butylene 2, 5-FDCA oligoesters -- c(EF)n cyclic ethylene 2, 5-FDCA oligoesters -- CALB Candida antarctica Lipase B -- COEs cyclic oligoesters -- DABP 4, 4′-diacetoxybiphenyl -- DAI 1, 4:3, 6-dianhydro-L-iditol -- DAM 1, 4:3, 6-dianhydro-D-mannitol -- DAS 1, 4:3, 6-dianhydro-D-sorbitol -- DCM dichloromethane -- DI polydispersity index -- DMF dimethyl furan -- DMF dimethylformamide -- DMFD dimethyl-2, 5-furan dicarboxylate ester -- DMSO dimethylsulfoxide -- DSC differential scanning calorimetry -- EG ethylene glycol -- FDCA furandicarboxylic acid -- GHG greenhouse gas -- GPC gel permeation chromatography -- HMF hydroxymethylfurfural -- LC liquid crystalline -- LC/TOF-MS liquid chromatography/time-of-flight mass spectrometry -- Mt metric tonnes -- Mw molecular weight -- NMR nuclear magnetic resonance -- NREU non-renewable energy use -- PAA poly(adipic acid) -- PBAF poly(butylene adipate-co-butylene furandicarboxylate) -- PBF poly(butylene 2, 5-furanoate) -- PBF-PTMG poly(butylene furandicarboxylate)-b-poly(tetramethylene glycol) copolymers -- PBHMF poly(2, 5-furandimethylene-2, 5-furandicarboxylate) -- PBIS poly(butylene-co-isosorbide succinate) -- PBS poly(butylene succinate) -- PBSebF poly(butylene sebacate-co-furanoate) -- PBSF poly(butylene succinate-co-butylene furandicarboxylate) -- PBST poly(butylene succinate-co-terephthalate) -- PBT poly(butylene terephthalate) -- PBT poly(butylene terephthalate) -- PCL poly(ε-caprolactone) -- PDAIF polyester from 2, 5-furandicarboxyl chloride and isoiodide -- PDASF polyester from 2, 5-furandicarboxyl chloride and D-isosorbide -- PDeF poly(decylene furanoate) -- PDMPF poly(2, 2-dimethyl-1, 3-propylene furanoate) -- PDoF poly(dodecylene furanoate) -- PE polyethylene -- PEF poly(ethylene 2, 5-furanoate) -- PEFS poly(ethylene 2, 5-furandicarboxylate-co-ethylene succinate) -- PEN poly(ethylene napthalate) -- PET poly(ethylene terephthalate) -- PHA polyhydroxyalkanoate -- PHepF poly(hepthylene furanoate) -- PHF poly(hexylene 2, 5-furandicarboxylate) -- PHMBF poly(1, 4-phenylbismethylene-2, 5-furandicarboxylate) -- PHQF poly(1, 4-phenylene-2, 5-furandicarboxylate) -- PHQH (poly(1, 4-phenylene-2, 5-furandicarboxylate) -- PLA poly(lactic acid) -- PLGA polylactide-glycolide -- PNF poly(nonylene furanoate) -- POF poly(octylene 2, 5-furandicarboxylate) -- POM polarized optical microscopy -- PPeF poly(pentylene furanoate) -- PPF poly(propylene 2, 5-furandicarboxylate) -- PPN poly(propylene napthalate) -- PPT poly(propylene terephthalate) -- PTMG poly(tetramethylene glycol) -- PTT poly(trimethylene terephthalate) -- Py-GC/MS pyrolysis-gas chromatography/mass spectroscopy -- ROP ring opening polymerization -- SSP solid state polymerization -- TBT tetrabutyl titanate -- TCE tetrachloroethane -- TGA thermogravimetric analysis -- THF tetrahydrofuran -- TiBO titanium (IV) n-butoxide -- TMDSC temperature-modulated differential scanning calorimetry -- UPRs unsaturated polyester resins -- UPs unsaturated polyesters -- WAXS wide-angle X-ray scattering -- φBF butylene furanicarboxylate unit content; Polymers -- Periodicals; Polymerization -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; Polymerization; Polymers; Periodicals; Electronic journals; 547.705
• DOI: 10.1016/j.eurpolymj.2016.08.004
• Languages: English
• ISSNs: 0014-3057

Abstract

Graphical Abstract: Abstract: Polymers based on 2, 5-furandicarboxylic acid (2, 5-FDCA), consist a new class of alipharomatic polyesters that can be prepared from monomers derived straight from renewable resources like furfural and hydroxymethylfurfural (HMF). For this reason, this class of materials has recently gained high interest. This review highlights the progress and fundamental aspects for the synthesis of bio-based 2, 5-FDCA polyesters and their thermal properties. During time, several techniques, catalysts and conditions have been suggested in the literature for the synthesis of furan-based polyesters and are presented here. Some problems associated with the coloration and successful syntheses of polyesters with high molecular weights are thoroughly discussed in the current review. Moreover, the thermal properties of the resulting materials have been presented in detail, as they constitute some of the most important parameters for use and processing. Finally, the preparation and properties such as biodegradability of several furanoate-based copolymers are also discussed.