Fabrication of new superconducting materials, CaxK1−xCy (0 < x < 1). (April 2016)

• Record Type: Journal Article
• Authors: Nguyen, Huyen T.L.; Nishiyama, Saki; Izumi, Masanari; Zheng, Lu; Miao, Xiao; Sakai, Yusuke; Goto, Hidenori; Hirao, Naohisa; Ohishi, Yasuo; Kagayama, Tomoko; Shimizu, Katsuya; Kubozono, Yoshihiro
• Is Part Of: Carbon. Volume 100(2016)
• Page Start: 641
• Page End: 646
• Publication Date: 2016-04
• Subjects: Carbon -- Periodicals; Carbone -- Périodiques; Koolstof; Toepassingen; Electronic journals; 546.681
• DOI: 10.1016/j.carbon.2016.01.071
• Languages: English
• ISSNs: 0008-6223

Abstract

Abstract: Metal intercalation to graphite produces various types of superconductors. The highest superconducting transition temperature T c (onset temperature, T c onset, of 11.5 K) was found in Ca intercalated graphite, denoted CaC6 . T c onset increased up to 15.1 K at 7.5 GPa, implying a positive pressure dependence. However, no new metal-intercalated graphite superconductors with T c onset higher than 11.5 K at ambient pressure have so far been reported. To search for new graphite superconductors, we successfully synthesized binary-element-intercalated graphite, Cax K1−x Cy . Their structure resembles that of KC8 . T c increased continuously with increasing x. Furthermore, the pressure dependence of T c in Ca0.6 K0.4 C8 was investigated over a wide pressure range from 0–43 GPa. T c (= 9.6 K at 0 GPa) increased to 11.6 K at 3.3 GPa, and decreased to 2.0 K at 41 GPa. This behavior is similar to that of CaC6, albeit with a lower maximum T c . X-ray diffraction patterns were measured under high pressures of 0–24 GPa, and suggest a structural transition at 15 GPa. Evidence is given for superconducting graphite involving binary metal intercalation.