Measurements of liquid phase residence time distributions in a pilot-scale continuous leaching reactor using radiotracer technique. (March 2015)

• Record Type: Journal Article
• Authors: Pant, H.J.; Sharma, V.K.; Shenoy, K.T.; Sreenivas, T.
• Is Part Of: Applied radiation and isotopes. Volume 97(2015:Mar.)
• Page Start: 40
• Page End: 46
• Publication Date: 2015-03
• Subjects: Uranium -- Continuous leaching reactor -- Residence time distribution -- Mean residence time -- Radiotracer -- Dead volume -- Tanks-in-series model; Radiology -- Periodicals; Radiation -- Industrial applications -- Periodicals; Nuclear chemistry -- Periodicals; Internet resource; Periodical; 660.298
• DOI: 10.1016/j.apradiso.2014.12.010
• Languages: English
• ISSNs: 0969-8043

Abstract

Abstract: An alkaline based continuous leaching process is commonly used for extraction of uranium from uranium ore. The reactor in which the leaching process is carried out is called a continuous leaching reactor (CLR) and is expected to behave as a continuously stirred tank reactor (CSTR) for the liquid phase. A pilot-scale CLR used in a Technology Demonstration Pilot Plant (TDPP) was designed, installed and operated; and thus needed to be tested for its hydrodynamic behavior. A radiotracer investigation was carried out in the CLR for measurement of residence time distribution (RTD) of liquid phase with specific objectives to characterize the flow behavior of the reactor and validate its design. Bromine-82 as ammonium bromide was used as a radiotracer and about 40–60 MBq activity was used in each run. The measured RTD curves were treated and mean residence times were determined and simulated using a tanks-in-series model. The result of simulation indicated no flow abnormality and the reactor behaved as an ideal CSTR for the range of the operating conditions used in the investigation. Highlights: Radiotracer technique was applied for evaluation of design of a pilot-scale continuous leaching reactor. Mean residence time and dead volume were estimated. Dead volume was found to be ranging from 4% to 15% at different operating conditions. Tank-in-series model was used to simulate the measured RTD data and was found suitable to describe the flow in the reactor. No flow abnormality was found and the reactor behaved as a well-mixed system. The design of the reactor was validated.