Metal-free trifluoroethylation of activated alkenes: rapid access to construct fluorinated 3, 3-disubstituted 2-oxindoles. Issue 44 (4th November 2015)
- Record Type:
- Journal Article
- Title:
- Metal-free trifluoroethylation of activated alkenes: rapid access to construct fluorinated 3, 3-disubstituted 2-oxindoles. Issue 44 (4th November 2015)
- Main Title:
- Metal-free trifluoroethylation of activated alkenes: rapid access to construct fluorinated 3, 3-disubstituted 2-oxindoles
- Authors:
- Mai, Wen-Peng
Sun, Bin
Qian, Guan-Sheng
Yuan, Jin-Wei
Mao, Pu
Yang, Liang-Ru
Xiao, Yong-Mei - Abstract:
- Abstract: A novel and mild fluorination/cyclization reaction of activated alkenes under metal-free conditions has been developed. Fluorinated radicals were produced from halogenated hydrocarbons by simple rongalit, meanwhile, no metal and extra base are needed. This method provides a general and rapid route to construct fluorinated 2-oxindoles in aqueous solution. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 71:Issue 44(2015)
- Journal:
- Tetrahedron
- Issue:
- Volume 71:Issue 44(2015)
- Issue Display:
- Volume 71, Issue 44 (2015)
- Year:
- 2015
- Volume:
- 71
- Issue:
- 44
- Issue Sort Value:
- 2015-0071-0044-0000
- Page Start:
- 8416
- Page End:
- 8423
- Publication Date:
- 2015-11-04
- Subjects:
- Metal-free -- C–H functionalization -- Fluorination -- Radical -- Cyclization
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2015.09.004 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 7336.xml