Nitrous oxide and methane emissions and nitrous oxide isotopic composition from waste incineration in Switzerland. (January 2015)

• Record Type: Journal Article
• Authors: Harris, Eliza; Zeyer, Kerstin; Kegel, Rainer; Müller, Beat; Emmenegger, Lukas; Mohn, Joachim
• Is Part Of: Waste management. Volume 35(2015)
• Page Start: 135
• Page End: 140
• Publication Date: 2015-01
• Subjects: Waste incineration -- Nitrous oxide -- Emission factor -- deNOx technology -- Greenhouse gas -- Isotopic composition; Hazardous wastes -- Periodicals; Refuse and refuse disposal -- Periodicals; 363.728
• DOI: 10.1016/j.wasman.2014.10.016
• Languages: English
• ISSNs: 0956-053X

Abstract

Highlights: N2 O emissions from waste incineration with SNCR NOx removal are 51.5 ± 10.6 g t −1 . This is significantly lower than the reported Swiss emission factor of 120 g t −1 (FOEN, 2013 ). N2 O contributes <0.3% and ≈ 2.5% of GHG emissions from SCR and SNCR plants. Measured isotopic SP of 17.7‰ is likely characteristic for N2 O emissions from SNCR. CH4 emitted by waste incineration is negligible, contributing < 0.01% to total GHGs. Abstract: Solid waste incineration accounts for a growing proportion of waste disposal in both developed and developing countries, therefore it is important to constrain emissions of greenhouse gases from these facilities. At five Swiss waste incineration facilities with grate firing, emission factors for N2 O and CH4 were determined based on measurements of representative flue gas samples, which were collected in Tedlar bags over a one year period (September 2010–August 2011) and analysed with FTIR spectroscopy. All five plants burn a mixture of household and industrial waste, and two of the plants employ NOx removal through selective non-catalytic reduction (SNCR) while three plants use selective catalytic reduction (SCR) for NOx removal. N2 O emissions from incineration plants with NOx removal through selective catalytic reduction were 4.3 ± 4.0 g N2 O tonne −1 waste (wet) (hereafter abbreviated as t −1 ) (0.4 ± 0.4 g N2 O GJ −1 ), ten times lower than from plants with selective non-catalytic reduction (51.5 ± 10.6 g N2 O t −1 ; 4.5 ± 0.9 g N2 O GJ −1 ). These emission factors, which are much lower than the value of 120 g N2 O t −1 (10.4 g N2 O GJ −1 ) used in the 2013 Swiss national greenhouse gas emission inventory, have been implemented in the most recent Swiss emission inventory. In addition, the isotopic composition of N2 O emitted from the two plants with SNCR, which had considerable N2 O emissions, was measured using quantum cascade laser spectroscopy. The isotopic site preference of N2 O – the enrichment of 14 N 15 NO relative to 15 N 14 NO – was found to be 17.6 ± 0.8‰, with no significant difference between the two plants. Comparison to previous studies suggests SP of 17–19‰ may be characteristic for N2 O produced from SNCR. Methane emissions were found to be insignificant, with a maximum emission factor of 2.5 ± 5.6 g CH4 t −1 (0.2 ± 0.5 g CH4 GJ −1 ), which is expected due to high incinerator temperatures and efficient combustion.