Syntheses, structures and photocatalytic degradation of organic dyes for two isostructural copper coordination polymers involving in situ hydroxylation reaction. Issue 9 (3rd May 2018)

• Record Type: Journal Article
• Authors: Peng, Yan-Fen; Qian, Lin-Lu; Ding, Jian-Gang; Zheng, Tian-Rui; Zhang, Ya-Qian; Li, Bao-Long; Li, Hai-Yan
• Is Part Of: Journal of coordination chemistry. Volume 71:Issue 9(2018)
• Page Start: 1392
• Page End: 1402
• Publication Date: 2018-05-03
• Subjects: Coordination polymer -- in situ hydroxylation -- photocatalytic degradation -- copper(II) compound -- fumarate; Coordination compounds -- Periodicals; 541.2242
• DOI: 10.1080/00958972.2018.1460664
• Languages: English
• ISSNs: 0095-8972

Abstract

Abstract: Two copper(II) coordination polymers, {[Cu2 (btre)(hsuc)Cl(H2 O)]·1.5H2 O}n (1 ) and {[Cu2 (btre)(hsuc)Br(H2 O)]·1.5H2 O}n (2 ) (btre = 1, 2-bis(1, 2, 4-triazol-4-yl)ethane, H3 hsuc = 2-hydroxysuccinic acid), were synthesized by the hydrothermal method via in situ hydroxylation reaction with fumarate (fum), btre and CuCl2 /CuBr2, and characterized by elemental analyses, IR, TG and X-ray diffraction.1 and2 are isostructural and show a 4-connected 2-D network based on [Cu2 O] dimers.1 and2 show good photocatalytic activity for the degradation of organic dyes methylene blue and methyl orange under UV light irradiation. Abstract :